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"An excellent text, highly recommended." — Choice
When it was first published, this first-year chemistry text revolutionized the teaching of chemistry by presenting it in terms of unifying principles instead of as a body of unrelated facts. Those principles included modern theories of atomic and molecular structure, quantum mechanics, statistical mechanics and thermodynamics. In addition, Dr. Pauling attempted to correlate the theories with descriptive chemistry, the observed properties of substances, to introduce the student to the multitude of chemical substances and their properties.
In this extensively revised and updated third edition, the Nobel Prize–winning author maintains an excellent balance between theoretical and descriptive material, although the amount of descriptive chemistry has been decreased somewhat, and the presentation of the subject, especially in relation to the nonmetals, has been revised in such a way as to permit greater correlation with the electronic structure of atoms, especially electronegativity.
The principles of quantum mechanics are discussed on the basis of the de Broglie wavelength of the electron. The quantized energy levels of a particle in a box are derived by means of a simple assumption about the relation of the de Broglie waves to the walls of the box. No attempt is made to solve the Schrodinger wave equation for other systems, but the wave functions of hydrogen-like electrons are presented and discussed in some detail, and the quantum states for other systems are also covered. Statistical mechanics is introduced before thermodynamics, and the discussion of thermodynamics is based on it. This arrangement reflects the author's belief that beginning students can understand statistical mechanics better than chemical thermodynamics.
Aimed at first-year college students who plan to major in chemistry or closely related fields, the book is written in a logical, clear and understandable style. In addition, many excellent figures are included, along with numerous problems and 75 pages of appendixes covering such topics as symmetry of molecules and crystals, hybrid bond orbitals, and magnetic properties of substances.
- Sales Rank: #271221 in eBooks
- Published on: 2014-11-24
- Released on: 2014-11-24
- Format: Kindle eBook
About the Author
Linus Pauling: Two-Time Nobel Laureate
In 1985 Dover reprinted Introduction to Quantum Mechanics with Applications to Chemistry, a well-known older book by Linus Pauling and E. Bright Wilson. This book had been first published fifty years earlier and remarkably still found readers in 1985, and still does today, twenty-five years further on.
The first edition of Pauling's General Chemistry was a short book of less than 250 pages published in 1944, during World War II. Three years later, it had more than doubled in size to almost 600 pages, and the 1953 edition was over 700 pages. Fifteen years later, for the 1970 edition, it reached its final size and configuration at almost 1,000 pages ― and that is the edition which Dover reprinted in 1988. Dr. Pauling's one request at that time was that we keep the price affordable for students.
Linus Pauling is of course the only Dover author to win two Nobel prizes, for Chemistry in 1954 and for Peace in 1962; he is the only winner in history of two unshared Nobel Prizes.
In the Author's Own Words:
"Satisfaction of one's curiosity is one of the greatest sources of happiness in life."
"Do unto others 20% better than you would expect them to do unto you, to correct for subjective error."
"The way to get good ideas is to get lots of ideas, and throw the bad ones away."
"Facts are the air of scientists. Without them you can never fly." — Linus Pauling
Critical Acclaim for General Chemistry:
"An excellent text, highly recommended." — Choice
Most helpful customer reviews
199 of 205 people found the following review helpful.
The Best Undergraduate Text ever!
By Ash Jogalekar
When Linus Pauling was teaching undergraduates at Caltech, he found that none of the existing undergrad texts would serve his purpose.So he decided to write his own. This was in the 1940's. The result, 'General Chemistry', even after more than 50 years, is one of the best introductions to chemistry at the University level that I know of. I discovered this book in my sophomore year and after that I couldn't put it down. If you really read this book thoroughly, you can probably say that you have an excellent grasp of most of the fundamental principles of chemistry. Pauling's masterly style of explaining the essentials without compromising on information is unmatched. The small, simple calculations that he illustrates in each chapter are enlightening. In addition, the book is lavishly illustrated with beautiful figures by Roger Hayward. Pauling has a special knack of bringing out the flavor of seemingly boring but important topics like thermochemistry and ionic equilibrium. If you want one book that will launch your chemical knowledge on the right trajectory, trust me and buy this one. You will be enlightened by it forever.
121 of 126 people found the following review helpful.
full of insight but eccentric
By Einsteinian
This is an interesting, if somewhat dated and eccentric textbook by the man who was probably the leading chemist of the twentieth century. It is full of interesting insight, and written with real flair, so much unlike the typical textbook today produced by the textbook publishing machines.
Let me give a couple of examples, good and bad, of what makes this book interesting, but also exasperating.
The book is the only freshman chemistry text I know of that has a derivation of the Boltzmann distribution P ~ e^(-E/kT), a very basic relation in the kinetic theory of gases and in fact in all of statistical physics. The derivation is simpler than most, which makes it a real jewel especially at this level, where most people would think it doesn't belong.
On the other hand, the section on chemical bonding, which is actually where Pauling made his reputation, is very eccentric, like the author, so much so that it makes the book unsuitable as the sole text for a course. It is all based on sp3 hybrid orbitals. As far as I can tell, sp2 and sp hybrids are never mentioned. With the sp3 story, Pauling is able to account surprisingly well for some systematics of bond lengths. Whether this is fortuitous or not, I don't know, but it is interesting. On the other hand, without sp2 and sp hybrids, he is completely unable to give the standard, very simple, beautiful account of bond angles. A student learning introductory chemistry from this text who then went into organic chemistry would soon be at a disadvantage without knowing the theory of hybrid orbitals that everyone else would get from any of the standard contemporary texts.
My recommendation: use this text as a very insightful, quirky supplement. The price is certainly right.
The text that comes closest, in my opinion, in seriousness, if not eccentricity, is the contemporary text by Oxtoby and coauthors. It is too highbrow though for most college introductory chemistry courses.
63 of 64 people found the following review helpful.
Despite its age, still a truly fine book.
By A Customer
Even though this is NOT the most up to date and technically correct text out there, it is still the best introduction to general chemistry I've seen which is why I rated it 5 stars (I refuse to dock it points for being old, unlike other reviews of other books I've seen). I found a copy at a garage sale, best four bucks I've spent in a while. The format of this book is superb, basing thermodynamics on his discussion of statistical mechanics and QM-he found it makes learning much more smooth, and I happen to agree. If someone would get permission to update this book and not much more, perfect general chem text for a college sequence. For those who'd like more physical and mathematical detail, the appendices are chock full of derivations, integrations and connections to make your heart swoon. Excellent book.
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